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I. Name ionic compounds

A. Naming compounds with type I cations-type I cations are cations that have one possible charge.
All the elements in the first two families form type I cations. A few of the elements in groups 3 though 13 form only one cation; therefore, a few of them are type I cations-examples include Ag+, Cd2+, Zn2+, and Al3+.

The cation is named first.

If the cation is a "simple" cation ("simple" ion is made from only one element.) the cations is named after the element.

If the cation is a polyatomic cation (a polyatomic ion is made from two or more covalently bonded elements.) you use the name that you have memorized (however, since we only talk about a couple of polyatomic cations this should not prove to be too difficult. NH4+ is the ammonium ion. The Hg22+ cation is a polyatomic ion and a type II cation.).

 

The anion is named second.

If the anion is a simple ion it takes its name from the root name of the element , and "-ide " is added.

If the anion is a polyatomic anion you use the name that you have memorized.

 

NaCl, MgCl2, AlCl3, NaNO3, BaSO4, (NH4)2SO3

B. Naming compound with type II cations-type II cations are capable of having several charges.
If the cation is not from group 1 or 2, or is not Ag+,Cd2+, Zn2+, or Al3+ then assume the cation is a type II cation.

 

The cation is named first and the charge of the cation is expressed as a Roman numeral.

Occasionally suffixes, -ic and -ous, are used; however, we will not be using them. -ic is for the higher charged cation, -ous is for the lower charged cation. For example ferric is Fe3+ and ferrous is Fe2+.

If the cation is a "simple" cation the cation is simply the name of the element.

If the cation is a polyatomic you use the name that you have memorized. However, since we only talk about one polyatomic type II cation this should not prove to be difficult. Hg22+ is mercury (I).

 

The anion is named second.

If the anion is a simple ion it takes its name from the root name of the element , and -ide is added.

If the anion is a polyatomic anion you use the name that you have memorized.

 

Fe3O2, CrCl3, MnO, Cu(NO3)2, Hg2Cl2

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Nomenclature

Please forward any suggestions or corrections to Christopher Masi